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Voltammetric study of electrochemical reduction of silicon ions at the electrodes of silver and glassy carbon in melt KF-KCl-K2SiF6

Annotation

Electroreduction of silicon ions is studied at glassy carbon and silver substrates in the melt KF-KCl-K2SiF6 in an inert atmosphere at temperatures of 700 and 725 ºC by linear voltammetry. The irreversibility of the process is set. The diffusion coefficients of Si4+ ions in the melt and transfer coefficients ά are defined.

Keywords

molten salt; silicon; linear voltammetry; irreversible process

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UDC

544.65:544.4:546.28

Pages

2201-2204

Received

2013-05-15

Section of issue

Section 1. KINETICS OF ELECTRODE PROCESSES

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