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Investigation of mechanism of cathode processes on cobalt silicides by electrochemical impedance spectroscopy method
The analysis of the mechanism of the cathode process of hydrogen evolution on cobalt silicides (CoSi2 and Co2Si) in sulfate solutions with different concentration of hydrogen ions, based on the results of the polarization and impedance measurements, is performed. The conclusion is made about the influence of thin oxide layers on the silicide surface on the kinetics and mechanism of hydrogen evolution.
hydrogen evolution reaction; silicide; impedance
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Section 1. KINETICS OF ELECTRODE PROCESSES
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