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Anodic selective dissolution of homogeneous gold and palladium alloys with copper and silver: surface development and heterogeneous nucleation

Annotation

Kinetic laws of the nucleation step of phase transformation of gold and palladium in the morphologically unstable surface layer of Ag-Au, Cu-Au and Ag-Pd alloys, subjected to selective dissolution in acid medium at supercritical conditions of anodic polarization, are established.

Keywords

selective dissolution of alloys; surface development; phase transformation; heterogeneous nucleation

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UDC

541.135.5:138.2

Pages

2212-2216

Received

2013-05-15

Section of issue

Section 1. KINETICS OF ELECTRODE PROCESSES

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